10 Celebrity Wives Who Were Mistresses First

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#9: Angelina Jolie

Photo Source: Whslionspride.com

Photo Source: Whslionspride.com

The Brangelina love affair began in 2004 while filming Mr. & Mrs. Smith. During that time, Brad was still married to Jennifer Aniston. The two separated in 2005 after which Brad and Angelina came out with their relationship in public and a baby on the way. They got married in 2014 and are still going strong. The couple has six children.

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